if so, echoing what it-ogo said in my opinion Belarusian is a tad closer to Russian lexically but Ukrainian is closer sonically
i'd start with Ukrainian, cause if you plan to continue on to Belarusian after that, knowing Ukrainian will help you tremendously on the lexical front
Belarusian is somewhere in the middle between the two other languages (totally subjective), so knowing the extremes you'll be able to crossbreed them